Synthesis of fluorinated phosphorus-containing copolymers and their immobilization and properties on stainless steel

A series of fluorinated-phosphonic acid methacrylates were synthesized by free radical polymerization using heptadecafluorodecyl methacrylate (HDFDMA) and (dimethoxyphosphoryl) methyl methacrylate (DMPMM) monomers for potential application as anti-corrosion coatings. The dimethyl protecting groups were then hydrolyzed, giving phosphonic acid groups that are able to stably bind onto metal oxide surfaces. The copolymers were then immobilized as a monolayer film to the surface of 316L stainless steel by treatment of dilute solutions in trifluoroacetic acid for 30 minutes followed by rinsing. The surfaces were analyzed using various techniques and contact angles as high as 128 degrees were recorded for some copolymer functionalized surfaces. Results also demonstrated that the polymer films proved stable to hydrolysis over several weeks of immersion in water.