Diffuse phthalate acid esters losses induced from large amount of agricultural plastic film residues caused low risks for water quality in China during 1991-2017

Extensive application of agricultural plastic films has resulted in abundant film residues in farmlands. Phthalate acid esters (PAEs) are vital additives of the agricultural plastic film and are easily emitted into soils. However, spatio-temporal variations of diffuse PAEs loss to water bodies have not been explored in China. This study used an integrated estimation framework and high-resolution activity data to conduct a comprehensive inventory of diffuse PAEs loss associated with plastic films of six main crop types in China for 1991-2017. We found that the diffuse PAEs loss induced from agricultural plastic films increased 10.57-46.30 kg over the same time. Di-butyl phthalate (DBP) and bis(2-ethylhexyl) phthalate (DEHP) accounted for ~75% of the national total loss. High PAEs loss regions are mainly located in Eastern China, the Middle-Lower Yangtze Plain, and eastern Yunnan and Sichuan provinces. We proved that PAEs emission, agricultural film residues, surface runoff, precipitation, and soil organic carbon explained 19.64%, 17.50%, 15.45%, 12.88%, and 9.83% of the total variation, respectively. The potential ecological risks to the various aquatic species were assessed to be low. Overall, our results are valuable for addressing severe agricultural plastic film residues and associated pollutant emissions and losses in China.