Methyl 4-{N′-[(1E)-1-(pyrazin-2-yl)ethylidene]hydrazinecarbonyl}benzoate
IUCrData(2018)
摘要
The title Schiff base, C15H14N4O3, was synthesized by the condensation reaction between caprylic hydrazide and 2-acetylpyrazine. There are two independent pseudo-enantiomeric molecules, A and B, in the asymmetric unit that differ mainly in the orientation of the hydrazone units. For example, the dihedral angles between the benzene and pyrazine rings are 20.836 (13) (A) and 15.701 (14)° (B). The molecular packing features N—H⋯O hydrogen bonds that lead to a twisted supramolecular chain along the b-axis direction. The presence of C—H⋯O interactions consolidates the chains into a three-dimensional architecture. The studied sample was a two-component twin.
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关键词
crystal structure,Schiff base,acylhydrazone ligand,hydrogen bonding
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