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Synthesis, Structure and Magnetic Property of a Tricapped Trigonal Prismatic TbIII-Based 3D-4F Complex

Jia-Jia Zhuang,Ming-Guang Chen, Yan-Bing Sun, Pei Hang, Yang Sui,Jia-Ping Tong

IOP conference series Materials science and engineering（2020）

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Abstract
Abstract A novel 3d-4f CoII/TbIII cluster [Co6Tb(Pic)6O3Cl3](H2O)6 (1) (Pic = 2-Picolinic acid) has been synthesized and characterized via X-ray crystallographic and magnetic measurements. X-ray crystallographic and continued shape measurements analysis revealed that the central Terbium (III) is coordinated in TbO9 geometry with D 3h symmetry. Magnetic studies indicated the complex presents a magnetic anisotropy with ferrimagnetic interactions.
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