ChemInform Abstract: Silicon‐Oxygen Bond‐Forming Reactions Upon Addition of Silanes and Silyl Halides to the 16‐electron Alkoxyiridium Complexes Trans‐roir(co)(p(p‐tol)3)2 (R: Me or Ph; P‐tol: P‐tolyl). Crystal and Molecular Structure of H2Ir(CO)(SiMe2Ph)(P(p‐tol)3)2.
ChemInform（1989）
摘要
AbstractThe silanes (II) add oxidatively to the alkoxo‐Ir complexes (I); the resulting complexes undergo reductive elimination of the alkoxysilanes (IV) with ultimate formation of the dihydridosilyl‐Ir(III) complexes (III).
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