Construction of a (Nnn)ru-Incorporated Porous Organic Polymer with High Catalytic Activity for Β-Alkylation of Secondary Alcohols with Primary Alcohols
Polymers(2022)
摘要
Solid supports functionalized with molecular metal catalysts combine many of the advantages of heterogeneous and homogeneous catalysis. A (NNN)Ru-incorporated porous organic polymer (POP-bp/bbpRuCl3) exhibited high catalytic efficiency and broad functional group tolerance in the C–C cross-coupling of secondary and primary alcohols to give β-alkylated secondary alcohols. This catalyst demonstrated excellent durability during successive recycling without leaching of Ru which is ascribed to the strong binding of the pincer ligands to the metal ions.
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关键词
heterogeneous catalysis,porous organic polymer,Ru NNN pincer complex,β-alkylation of secondary alcohols
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