Synthesis Of 3-Hydroxybutyraldehyde Over Highly Stable Solid Base Catalysts Prepared From Layered Double Hydroxides
APPLIED CLAY SCIENCE(2021)
摘要
3-Hydroxybutyraldehyde (3-HBA) is an important intermediate for the manufacture of biodegradable plastics (polyhydroxyalkanoate), and it is of great significance to find an efficient way for the catalytic synthesis of 3-HBA from surplus acetaldehyde. In this work, a series of MgxAlO(x+1.5)-t (t referred to the calcination temperature) solid bases were prepared via the controlled calcination of MgxAl layered double hydroxides with different ratio of Mg/Al and tested in the aldol condensation of acetaldehyde to 3-HBA. Characterization results revealed that the formed MgO particles were embedded in magnesium aluminate spinel (MgAl2O4) in Mg3AlO4.5-1100, which exhibited excellent activity and stability in the continuous liquid flow condensation of acetaldehyde. The detected selectivity of 3-HBA reached 89.0% with a 73.8% conversion of acetaldehyde at 25 degrees C and WHSV-1 = 2.8 h. Meantime, Mg3AlO4.5-1100 catalyst could retain its activity within 300 h on stream. What's more, the reaction mechanism over Mg3AlO4.5-1100 catalyst was proposed according to the results of several experiments.
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关键词
Layered double hydroxides, 3-Hydroxybutyraldehyde, Acetaldehyde, Aldol condensation
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