The Synthesis And Crystal-Structure Of A Remarkable Binuclear, Double Pd-Cl-H-O-Pd Bridged Palladium Alcohol Complex - Catalytic Oxidations With Molecular-Oxygen Mediated By [([Me2c(Oh)Ch2conme2]Pd(Cl)No2)2]

Nh Kiers,Bl Feringa,H Kooijman,Al Spek,Pwnm Vanleeuwen

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS（1992）

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摘要

The Pd(Cl)NO2 complex of N,N-3-trimethyl-3-hydroxybutyramide is dimeric in the solid state with two Pd-Cl-H-O-Pd hydrogen-bond bridges; however, in solution the complex is monomeric and catalytically active in the oxidation of alkenes.

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关键词

palladium alcohol complex,catalytic oxidations,molecular oxygen,double pd–cl–h–o–pd

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