Catalytic Reduction of N2 to Borylamine at a Molybdenum Complex.
Angewandte Chemie(2021)
摘要
Catalytic formation of borylamines from atmospheric N-2 is achieved for the first time using a series of homogenous (triphosphine)Mo complexes. Stepwise functionalization of the (triphosphine)Mo-nitrido complex with chloroborane led to the synthesis of the imido complex. Electrochemical characterization of the (PPP)Mo-nitrido and (PPP)Mo-borylimido complexes showed that the latter is much more easily reduced.
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关键词
boranes,molybdenum,N-2 reduction,nitride functionalization,tridentate phosphine ligands
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