Synthesis Of Pyrrole-Based Poly(Arylenevinylene)S Via Co-Catalyzed Hydroarylation Of Alkynes
MACROMOLECULAR RAPID COMMUNICATIONS(2021)
摘要
Polyaddition via the Co-catalyzed hydroarylation of 1-(2-pyrimidinyl)pyrrole with aromatic diynes affords poly(arylenevinylene)s under mild conditions. This reaction avoids production of stoichiometric amounts of by-products. Although structural analysis of the obtained polymers reveals the presence of 1,1-vinylidene unit, switching the counter anion of the Co catalyst and steric hindrance of the diyne monomers improves the regioselectivity of the polymers. When a catalyst with bulky counter anions is used for the reaction of less hindered diyne monomers, 1,2-vinylene linkages are formed dominantly over 1,1-vinylidene linkages (93:7). The effect of the regioselectivity of the polymer on the optical and semiconducting properties is also evaluated.
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关键词
conjugated polymers, hydroarylation, polyaddition, poly(arylenevinylene)
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