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Synthesis, Crystal Structure, Gas Absorption, And Separation Properties Of A Novel Complex Based On Pr And A Three-Connected Ligand

CRYSTALS(2017)

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Abstract
A novel Pr complex, constructed from a rigid three-connected H(3)TMTA and praseodymium(III) ion, has been synthesized in a mixed solvent system and characterized by X-ray single crystal diffraction, infrared spectroscopy, a thermogravimetric analysis, an element analysis, and powder X-ray diffraction, which reveals that complex 1 crystallizes in a three-dimensional porous framework. Moreover, the thermal stabilities and the fluorescent and gas adsorption and separation properties of complex 1 were investigated systematically.
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Key words
rare earth complex,solvothermal conditions,thermal stabilities,fluorescent property,gas uptake
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