Β-Cyclodextrin–nhc–gold(i) Complex (Β-Icyd)aucl: A Chiral Nanoreactor for Enantioselective and Substrate-Selective Alkoxycyclization Reactions

Coralie Tugny,Natalia del Rio,Mehdi Koohgard,Nicolas Vanthuyne,Denis Lesage,Kajetan Bijouard,Pinglu Zhang,Jorge Meijide Suarez,Sylvain Roland,Etienne Derat,Olivia Bistri-Aslanoff,Matthieu Sollogoub,Louis Fensterbank,Virginie Mouries-Mansuy

ACS Catalysis（2020）

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摘要

NHC-capped β-cyclodextrin (β-ICyD) was used as a ligand for gold-catalyzed alkoxycyclization reactions. The cavity was found to be responsible for a triple selectivity: (i) the asymmetric shape of ...

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关键词

gold(I),asymmetric catalysis,selectivity,cyclodextrins,cavity

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