The Contributions of Socioeconomic and Natural Factors to the Acid Deposition over China

China has experienced severe acid rain pollution during the past decades due to excessive sulfur oxides (SO2) and nitrous oxides (NOx) emissions, which further caused lake acidification, biodiversity losses and climate change. Although the major sources of acid deposition have been clarified previously, the contributions of socioeconomic (natural) factors to the regional acid deposition remained unknown. Therefore, a series of valuable data including socioeconomic (natural) variables and measured pH value in the rainwater at the city level were collected to identify the key factors influencing the rainwater pH value at the national and the regional scale using the spatial econometric model/geographical detector technique and geographical weight regression (GWR) model, respectively. The results showed that the annual mean pH value in the rainwater in China was 6.54 +/- 0.72. The rainwater pH in winter (6.01 +/- 0.41) was significantly lower than those observed during summer (6.74 +/- 0.64), spring (6.71 +/- 0.71) and autumn (6.71 +/- 0.69). The spatial econometric model indicated that socioeconomic indicators including per capita gross industrial production (GIP), ratio of built-up area to the urban land (RBU), foreign direct investment (FDI), SO2 emission, and meteorological factors of annual mean precipitation (AMP), and annual mean relative humidity (AMRH) were the main factors for the acid deposition. The geographical detector technique implied that the power of determinants were in the order of AMRH (10.00%) = AMP (10.00%) > SO2 emission (8.51%) > FDI (8.32%) > RBU (7.64%) > per capita GIP (7.00%). The GWR implied that GIP, FDI, and SO2 emission made relatively higher contribution to acid deposition in East China relative to other regions owning to the huge population and the higher energy consumption. The higher rainfall amount and RH in Southeast China significantly increased the pollutant deposition fluxes and promoted the heterogeneous transformations of precursors of acid rain, respectively. The findings herein shed light upon the socioeconomic forces for the acid deposition in China for the first time and provided the new information for government sectors to control the acid rain pollution in the future. (C) 2020 Elsevier Ltd. All rights reserved.