Synthetic Studies on Bilobalide

Akihiro Shiogai,Tatsuya Toma,Satoshi Yokoshima

SYNLETT（2020）

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摘要

We disclose our synthetic studies on bilobalide, which features a Diels-Alder reaction of a cyclic anhydride to form two contiguous quaternary carbon centers, desymmetrization of a symmetric diol, and construction of a cyclic acetal under acidic conditions with inversion of configuration at an allylic position.

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关键词

desymmetrization,Diels-Alder reaction,Mukaiyama hydration,quaternary carbon,tertiary alcohol

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