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Voltammetric Determination of Formaldehyde at Low Concentrations in the Synthetic Fuel Oxymethylene Dimethyl Ether

Energy & fuels(2019)

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摘要
In this study, the formaldehyde content in the synthetic fuel oxymethylene dimethyl ether (OME) was measured with three different methods. The formaldehyde concentration was below 1000 mg/L. Only the voltammetric method showed no cross-sensitivity with degradation products of OME, possible fuel additives, and OME itself. The sodium sulfite titration method showed strong cross-sensitivities to formic acid and amine 2-amino-2-methyl-1-propanol. This amine also influenced the measurement result of the 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole method. In OME without degradation products and additives, the three investigated methods showed similar results.
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