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One step transformation of waste polyvinyl chloride to tantalum carbide@carbon nanocomposite at low temperature

JOURNAL OF THE AMERICAN CERAMIC SOCIETY(2019)

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摘要
With the increasing use of plastic products, the environmental pollution has become more and more serious, and it also prompts us to focus on the urgent problem: how do we deal with the waste plastic? This work develops a facile procedure to convert waste polyvinyl chloride (PVC) into tantalum carbide@carbon, via the chemical reaction of waste PVC, tantalum pentoxide, and metallic lithium in a stainless-steel autoclave at 700 degrees C. The structures, compositions, and morphologies of the as-obtained products have been investigated by X-ray diffraction pattern and electron microscopy. Furthermore, the effect of the reaction temperature on the composition and morphology of the as-obtained products has been investigated. The possible formation mechanism of tantalum carbide has also been briefly discussed.
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关键词
carbides,core-shell structures,nanocomposites,oxidation resistance,waste disposal
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