Electronic and bite angle effects in catalytic C–O bond cleavage of a lignin model compound using ruthenium Xantphos complexes
CATALYSIS SCIENCE & TECHNOLOGY(2017)
摘要
Bite angle and electronic effects on the ruthenium-diphosphine catalysed ether bond cleavage of the lignin beta-O-4 model compound 2-phenoxy-1-phenylethanol were tested. Enhanced conversion of the substrate was observed with increasing sigma-donor capacity of the ligands. Kinetic and thermodynamic data suggest oxidative addition of the dehydrogenated model compound to the diphosphine Ru(0) complex to be rate-limiting.
更多查看译文
关键词
lignin model compound,ruthenium xantphos complexes,catalytic
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要