FeCl3·6H2O-mediated reaction of [60]fullerene with amidoximes

Fang Fang,Jianmin Zhang, Lei Cao, Subo Shen,Yuwei Guo,Zhiqing He,Han Hu

Tetrahedron（2016）

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摘要

A FeCl3·6H2O-mediated reaction of [60]fullerene with amidoximes for the preparation of fulleroimidazolines has been presented. This reaction shows a wide substrate scope, and the products obtained from alkyl-substituted amidoximes are first disclosed. In addition, a possible mechanism is proposed.

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关键词

Fullerene,Amidoximes,FeCl3·6H2O,Fulleroimidazolines,1,3-Dipolar cycloaddition

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