Co-Assembly Kinetics of Graphene Oxide and Block Copolymers at the Water/Oil Interface.

The coassembly kinetics of graphene oxide (GO) nanosheets and diblock copolymers at the water/toluene interface is probed by tracking the dynamic interfacial tension using pendant drop tensiometry. The diblock copolymer significantly enhances the surfactancy of the GO nanosheets at the interface. It is found that diblock copolymers rapidly adsorb to the water/toluene interface and enhance the adsorption affinity of GO nanosheets to the interface. The continuous adsorption of GO at the interface leads to a random loose packing state, at which the adsorbed GO and diblock copolymers start to form an elastic film. After this transition, GO continues to adsorb to the interface, however, at a much slower speed, yielding a more solidlike elastic film in the long time equilibrium limit.