The Asymmetric Construction of CF3-containing Spiro-Thiazolone-pyrrolidine Compounds Via [3 + 2] Cycloaddition.
Organic & biomolecular chemistry(2019)
摘要
The first organocatalytic method for the asymmetric construction of CF3-containing spiro-thiazolone-pyrrolidine compounds has been developed. This is one of the very few methods to reach spiro-thiazolones, and afforded the products in excellent yields and stereoselectivities catalysed by only 1 mol% cinchona alkaloid-derived catalyst.
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