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Selenium dioxide-promoted selective synthesis of mono- and bis-sulfenylindoles

Samuel Thurow,Filipe Penteado,Gelson Perin,Diego Alves,Claudio Santi,Bonifacio Monti,Carl H. Schiesser,Thiago Barcellos,Eder J. Lenardão

Organic Chemistry Frontiers（2018）

Cited 27|Views27
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Abstract
A selective method for the preparation of mono- and bis-sulfenylindoles was developed using an oxidizing agent and the I-2/SeO2 system as an efficient catalyst. The selectivity was controlled by varying the amount of SeO2. This represents the first example of the application of SeO2 in this type of selective chemistry.
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Key words
selective synthesis,dioxide-promoted,bis-sulfenylindoles
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