Synthesis of thiophosphates through a three-component reaction by using sulfur dioxide as the sulfur source
Organic Chemistry Frontiers(2017)
摘要
Generation of thiophosphates through a three-component reaction of diaryliodonium tetrafluoroborates, 1,4-diazabicyclo[2.2.2]octane-sulfur dioxide (DABCO.(SO2)(2)), and diarylphosphine oxides under visible light irradiation is described. In this transformation, sulfur dioxide acts as the sulfur source, and reduction of arylsulfonyl radicals is the key step to fulfill the thiolation with diarylphosphine oxides.
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关键词
thiophosphates,sulfur dioxide,synthesis,three-component
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