The activation of CH bonds using an EmimAc/MWCNTs composite: a comparison of the composite used as electrolyte and electrode in aqueous media
Electrochimica Acta(2016)
摘要
An EmimAc/MWCNTs composite was prepared and characterized through SEM and TEM. The MWCNTs were well dispersed after combining with alkaline EmimAc. The activity of the composite was demonstrated by CV and controlled potential electrolysis. The composite could be used independently as electrolyte or electrode and showed excellent activity toward the electro-oxidation of the CH bond of benzylic systems, and did so at a lower oxidation potential than when using EmimAc or MWCNTs. After modification, the pH value of the composite was adjusted to the acid range, and the yield of aldehyde adducts obtained through electro-oxidation improved.
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关键词
EmimAc/MWCNTs composite,activation of CH bond,electro-oxidation
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