Site-Selective Ni-Catalyzed Reductive Coupling of Α-Haloboranes with Unactivated Olefins
Journal of the American Chemical Society(2018)
摘要
A mild, chemo- and site-selective catalytic protocol that allows for incorporating an alkylboron fragment into unactivated olefins is described. The use of internal olefins enables C-C bond-formation at remote sp3 C-H sites, constituting a complementary and conceptually different approach to existing borylation techniques that are currently available at sp3 centers.
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