Discovery and application of iminotriphenylphosphorane as a formal aromatic primary amine protecting group

Benedicte Delouvrie,Herve Germain,Craig S Harris,Maryannick Lamorlette,Honorine Lebraud,Ha Thi Hoang Nguyen,Anais F M Noisier,Gilles Ouvry

Tetrahedron Letters（2012）

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摘要

During our efforts to selectively synthesise N-arylated benzotriazole fragments, we developed a new primary aromatic amine protecting group strategy showing significant advantages over recognised protecting groups.

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关键词

Iminotriphenylphosphorane,Primary amine protecting group,Regioselective preparation of triazoles and benzotriazoles

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