A Moisture-Absorbing and Abrasion-Resistant Transparent Coating on Polystyrene

A common phenomenon concerning cold surfaces which are subjected to a warmer, more humid atmosphere is condensation in the form of water droplets (fogging) or even ice crystals (icing). Thus, a previously transparent object becomes opaque because light is scattered by the droplets or crystals. This may impair the usability of that object. We developed an anti-fogging/icing coating which overcomes the problem of fogging and icing by being able to absorb the condensing water and preventing it from crystallizing. The coating consists of poly(1-vinyl-2-pyrrolidone) (PVP) crosslinked by UV light using hydrogen peroxide (H 2 O 2 ). Benzophenone (BP) is used to attach PVP to the surface of the polystyrene (PS) substrate. At temperatures as low as −60°C, the PVP coating can absorb up to 70 wt% of water and still inhibit its crystallization. However, at surface temperatures of around −18°C, opacity is only observable at 150 wt% of absorbed water and higher. An increasing coating thickness as well as a decreasing crosslink density improves the anti-fogging/icing effect because the coating can absorb more water. The abrasion resistance of the coating is impaired by a decreasing crosslink density.