U-Pb age and origin of gem zircon from the New England sapphire fields, New South Wales, Australia

AUSTRALIAN JOURNAL OF EARTH SCIENCES(2012)

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Abstract
Chemical compositions and geochronological data utilising the laser ablation ICP-MS technique are presented for zircon megacrysts found in alluvial gem corundum deposits associated with Upper Cretaceous-Cenozoic alkali basalts in the Inverell district-New England field, New South Wales, eastern Australia. Three localities, Kings Plains, Swan Brook and Mary Anne Gully, produce gem-quality transparent dark brown and yellow zircon megacrysts, mostly under 10 mm in size. Although brown zircon shows relative enrichment in Hf and REE, there are no differences in relative transition metal concentrations between the colours. Chemical homogeneity within a single crystal indicates stable crystallisation conditions. The Pb-206/U-238 age of zircon megacrysts from these three localities define older and younger groups of 216-174 Ma and 45-37.7 Ma, respectively. The epsilon(Hf) values of zircon megacrysts from Kings Plains show +7.51+/-0.34 in the older group and +10.72+/-0.31 in the younger group. Swan Brook zircons give +11.54+/-0.47 and +8.32+/-0.58, and Mary Anne Gully zircons are +13.67+/-0.63 and +8.50+/-0.48, respectively. These zircons from New England alluvial gem deposits have two main formational events around Upper Triassic-Lower Jurassic and Eocene episodes. Most originated from lithospheric mantle and all were brought-up by later host basaltic magmas.
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Key words
Gem zircon,megacryst,U-Pb age,Hf isotopes,trace elements,alkali basalt,mantle,New England,NSW,East Australia
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