ChemInform Abstract: Divergent Chemo‐, Regio‐, and Diastereoselective Normal Electron‐Demand Povarov‐Type Reactions with Α‐oxo‐ketene Dienophiles.

Jaime Galvez,Juan‐Carlos Castillo,Jairo Quiroga,Michel Rajzmann,Jean Rodriguez,Yoann Coquerel

Chem Inform（2015）

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摘要

AbstractThe reaction between electron‐rich 2‐aza‐dienes (I), (IV), (VI), and (IX) and α‐oxo‐ketenes, derived from the Wolff rearrangement of 2‐diazocycloalkane‐diones such as (II) affords spiro hydropyridones (III) and (V) with good to excellent diastereoselectivity.

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