Synthesis in ionic liquids only: access to α-oxo-γ-thio-esters via Mukaiyama coupling

Khouloud Jebri,Marierose Mazieres,Stephanie Ballereau,Taicir Ben Ayed,Jeanchristophe Plaquevent,Michel Baltas,Frederic Guillen

Cheminform（2014）

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摘要

Ionic liquids are solvents general enough to conduct a multi-step process in organic synthesis. We show that both the preparation of starting materials (thioacetals and enoxysilane) as well as their coupling can be realized in such medium.

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关键词

Ionic liquid,Mukaiyama reaction,α-Oxo γ-thio-ester,Thioacetal,Enoxysilane,Ethyl pyruvate

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