Chiral Bis(Amino Alcohol) Silver Complex Derived from (+)-Camphor
Journal of coordination chemistry(2015)
摘要
A chiral silver(I) complex was synthesized from the reaction of a chiral amino alcohol derived from (+)-camphor and silver nitrate, with the structure unambiguously disclosed by X-ray analysis and 2-D-NMR experiments. In this complex, the amino alcohol molecule is a monodentate ligand through the amino nitrogen, requiring two amino alcohol units which are coordinated to the silver and located orthogonally through the NH-Ag-NH axis.
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关键词
Silver complex,Amino alcohol,(+)-Camphor
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