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Hydroxylation of Phenol on Iron-Containing Mesoporous Silica with Hierarchical Macroporous Architecture

Takashi Kamegawa,Takahiro Ando,Yasushi Ishiguro,Hiromi Yamashita

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN（2015）

Cited 11|Views2
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Abstract
Iron-containing mesoporous silica with hierarchical macroporous architecture (Fe-MMS) was prepared by applying a solvent evaporation method. In the hydroxylation of phenol with H2O2, the advantageous structure of Fe-MMS realized the higher selectivity for formation of dihydroxybenzene (catechol and hydroquinone) as compared to Fe-containing mesoporous silica (Fe-MS).
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Key words
mesoporous silica,phenol,iron-containing
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