Ready synthetic access to enantiopure allylic α(F)-branched fluoroalkenes.

Florent Larnaud,Julien Malassis,Emmanuel Pfund,Bruno Linclau,Thierry Lequeux

Organic letters（2013）

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摘要

Convenient access to homochiral fluoroalkenes is described via a Julia-Kocienski olefination reaction. The required homochiral fluorosulfone is synthesized by a Mitsunobu reaction from readily available enantiopure secondary alcohols.

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enantiopure allylic,ready synthetic access

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