An efficient and stereoselective synthesis of beta-D-Arap-(1-->2)-beta-D-Galp-(1-->3)-beta-D-Galp-(1-->4)-alpha-D-Manp, a tetrasaccharide fragment of Leishmania major lipophosphoglycan.

D V Yashunsky,A P Higson, A J Ross,A V Nikolaev

Carbohydrate research（2001）

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摘要

A tetrasaccharide fragment of Leishmania major lipophosphoglycan (which seems to be involved in a biological mechanism for the parasite transmission) has been synthesised using the thioglycoside, trichloroacetimidate and halide-exchange glycosylation procedures and step-wise chain elongation strategy.

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An efficient and stereoselective synthesis of beta-D-Arap-(1--&gt;2)-beta-D-Galp-(1--&gt;3)-beta-D-Galp-(1--&gt;4)-alpha-D-Manp, a tetrasaccharide fragment of Leishmania major lipophosphoglycan.

An efficient and stereoselective synthesis of beta-D-Arap-(1-->2)-beta-D-Galp-(1-->3)-beta-D-Galp-(1-->4)-alpha-D-Manp, a tetrasaccharide fragment of Leishmania major lipophosphoglycan.