Ligand-free palladium-catalyzed intramolecular Heck reaction of secondary benzylic bromides.

Wei Zhou,Guanghui An,Guangqian Zhang,Jianlin Han,Yi Pan

ORGANIC & BIOMOLECULAR CHEMISTRY（2011）

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摘要

A facile ligand-free palladium-catalyzed intramolecular Heck reaction of beta-hydrogen-containing secondary benzylic bromides was developed, which affords pyrroline derivatives with good regioselectivities.

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关键词

secondary benzylic bromides,ligand-free,palladium-catalyzed

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