Synthetic Studies of Moenomycin A Disaccharide Analogues. Protection of the Anomeric Centre with Long-Chain Protective Groups
Tetrahedron(1999)
摘要
Two new C9 protecting groups for the anomeric position of carbohydrates are reported. Methods both for their introduction and removal are described. The C9-protected compounds are much less polar than the corresponding allyl protected analogues. The new protecting group chemistry has been used to prepare compound 17 en route to a disaccharide analogue of the antibiotic moenomycin A.
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关键词
carbohydrates,protecting groups,antibiotics
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