Determination of the sources of toxic elements in environmental particles using microscopic and statistical analysis techniques

Samples of urban dust were physically fractionated into subsamples having unique size, density, ferromagnetism, and elemental compositional characteristics. The high density fractions containing the majority of each of the potentially toxic metals (Pb, Cd, Zn, Cr, Co, Mn) were subjected to X-ray microanalysis and to bulk analysis using instrumental neutron activation. Microanalysis was used to classify individual particles with respect to primary sources. The bulk analytical results were subjected to factor analysis to delineate the underlying factors (particle sources) responsible for the compositional variation in the subsamples. The advantages of the combined use of microanalytical and statistical techniques for source definition are described. X-ray microanalysis is used to substantiate the attribution of a given factor to a suspected particle source, to aid in the determination of the number of factors (sources) present, and to assess the extent to which a given factor represents a unique source of particles. Bulk analysis/factor analysis promotes the most effective use of X-ray microanalysis to characterize major particle types, and provides data on some toxic trace metals (e.g., Cd) that are not detectable using X-ray microanalysis. Target transformation factor analysis also is more useful in the quantitative determination of the relative mass contributions of major sources to the total dust sample.