Simultaneous formation of sorbitol and gluconic acid from cellobiose using carbon-supported ruthenium catalysts
Journal of Energy Chemistry(2013)
摘要
A carbon-supported Ru catalyst, Ru/BP2000, is able to simultaneously convert cellobiose into sorbitol and gluconic acid. This reaction occurs as the result of hydrolytic disproportionation in water at 393 K under an Ar atmosphere, without bases or sacrificial reagents. In-situ XANES measurements suggest that the active Ru species involved is composed of partially oxidized Ru metal.
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关键词
cellobiose,supported ruthenium catalyst,hydrolysis,disproportionation
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