SiC/SiO2 nanocables and nanosprings synthesized by catalyst-free method

Physica E: Low-dimensional Systems and Nanostructures(2006)

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摘要
High-yield and high-purity SiC/SiO2 nanocables and nanosprings were synthesized without the presence of catalyst by high frequency-induction heating of SiO and activated carbon fibers in the temperature of 1450°C for 10min. The as-prepared nanocables consist of a 10–25nm diameter single-crystalline core wrapped with an amorphous SiO2 shell of a diameter of 10–20nm. The nanosprings diameter and pitch of as-grown SiC/SiO2 are ∼25 and 10nm, respectively. The formation mechanism was analyzed by thermodynamics calculation combined with SEM, TEM and HRTEM.
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81.05.Hd,81.07.Bc,81.07.Vb,81.10.Bk
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