The structural characterization and hydroformylation activity of the tri-rhodium complex [Rh3(μ2-dppm)2(μ2-CO)3(K1-CO)3]BF4

Fabio Lorenzini,Eoghain O’Hara,Shimeng Qian,Fabio Marchetti,James M. Birbeck,Anthony Haynes,Alexander J. Blake,Graham C. Saunders,Andrew C. Marr

Inorganic Chemistry Communications（2009）

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摘要

Rh2(cod)2(μ2-dppm)(μ2-Cl)]BF4 rearranges under carbon monoxide to give [Rh3(μ2-dppm)2(μ2-CO)3(K1-CO)3]BF4. The tri-rhodium complex has been structurally characterized by single crystal X-ray crystallography. The hydroformylation activities of the complexes were compared for substrates styrene and 1-hexene and the activity of tri-rhodium complex found to be unexpectedly high.

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关键词

Binuclear,Trinuclear,Rhodium,Hydroformylation

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