Phase‐separated, Conducting Composites from Polyaniline and Benzobisthiazole Rigid‐rod Polymer
Journal of polymer science Part B, Polymer physics(2001)
摘要
As an alternative method for processing polyaniline (PANI) from its conducting (protonated) state, vacuum casting of PANI from a methanesulfonic acid (MSA) solution provided films with electrical conductivity values of about 130-150 S/cm. In addition, we similarly prepared blended films of PANI.MSA and poly(p-phenylene benzobisthiazole) (PBZT). This process eliminated the need for a subsequent protonation step and had the additional advantage that the conjugated PBZT may provide alternative conducting pathways. Conductivity values of the composite films ranged from 100 pS/cm to 124 S/cm, and the films displayed critical concentration behavior with a PANI threshold concentration of 2.75% and a critical exponent of 4. Transmission electron micrographs displayed phase-separated regions with PANI forming a continuous network at high concentrations. Thermogravimetric analysis results demonstrated the thermal and thermooxidative stability advantage of the blends due to the PBZT component. (C) 2001 John Wiley & Sons, Inc.
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关键词
polyaniline,poly(p-phenylene benzobisthiazole) (PBZT),conducting composites,conducting blends,rigid-rod polymers,TEM,percolation,critical concentration,critical exponent
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