Bis-benzyl protected 6-amino cyclitols are poisonous to Pd/C catalysed hydrogenolysis of benzyl ethers

M Bashir-Uddin Surfraz,Mahmoud Akhtar,Rudolf K Allemann

Tetrahedron Letters（2004）

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摘要

Pd/C and Pd(OH)2/C catalysts are both poisoned by bis-benzyl protected 6-aminocyclitols thereby inhibiting the hydrogenolysis of benzyl ethers but removing N-Cbz groups chemoselectively.

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关键词

Catalysis,Deprotection,Poison

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