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Metal-Free Living Cationic Ring-Opening Polymerization of Cyclic Esters Using Selenonium Salts As Lewis Acids

Wenjing Shu, Xiaoying Cheng, Yihan Gao,Xia Lin,Xiangqiang Pan,Jiajia Li,Jian Zhu

Polymer chemistry(2024)

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Abstract
Selenonium salts were employed as a new class of metal-free Lewis acid catalysts for the cationic ring-opening polymerization (ROP) of various cyclic esters. Polyesters with controlled molecular weights and narrow...
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