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Synthesis of (E)--Iodovinyl Sulfones via HI-mediated Vicinal Iodosulfonylation of Alkynes with Sodium Sulfinates

ASIAN JOURNAL OF ORGANIC CHEMISTRY(2024)

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摘要
Hydroiodic acid-mediated vicinal iodosulfonylation reaction of alkynes with sodium sulfinates is proposed for the synthesis of (E)-beta-iodovinyl sulfones. The method is easy to operate, environmentally friendly, using inexpensive and easily available raw materials, and giving the target products with good regio- and stereoselectivity in satisfactory yields.
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关键词
C-S,HI- mediated,Iodosulfonation,Radical addition,Viny sulfone
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