Finely manipulating room temperature phosphorescence by dynamic lanthanide coordination toward multi-level information security

Room temperature phosphorescence materials have garnered significant attention due to their unique optical properties and promising applications. However, it remains a great challenge to finely manipulate phosphorescent properties to achieve desirable phosphorescent performance on demand. Here, we show a feasible strategy to finely manipulate organic phosphorescent performance by introducing dynamic lanthanide coordination. The organic phosphors of terpyridine phenylboronic acids possessing excellent coordination ability are covalently embedded into a polyvinyl alcohol matrix, leading to ultralong organic room temperature phosphorescence with a lifetime of up to 0.629 s. Notably, such phosphorescent performance, including intensity and lifetime, can be well controlled by varying the lanthanide dopant. Relying on the excellent modulable performance of these lanthanide-manipulated phosphorescence films, multi-level information encryption including attacker-misleading and spatial-time-resolved applications is successfully demonstrated with greatly improved security level. This work opens an avenue for finely manipulating phosphorescent properties to meet versatile uses in optical applications. Room temperature phosphorescent materials have many desirable properties, but fine control of these can be challenging. Here, the authors report a strategy for this control by dynamic lanthanide coordination in combination with organic phosphors.