Hydroxylation of the indium tin oxide electrode promoted by surface bubbles

Adherent bubbles at electrodes are generally treated as reaction penalties. Herein, in situ hydroxylation of indium tin oxide surfaces can be easily achieved by applying a constant potential of +1.0 V in the presence of bubbles. Its successful hydroxylation is further demonstrated by preparing a ferrocene-terminated film, which is confirmed by cyclic voltammetry and X-ray photoelectron spectroscopy. A simple and effective strategy for hydroxylating the ITO surface with hydroxyl radicals produced by electrochemical oxidation of hydroxide anions at the gas bubble adherent electrode.