Reversible C-H sampling for direct functional translocation
CHEM CATALYSIS(2023)
Abstract
In a recent Nature issue, Xu et al. introduced a novel reversible C-H sampling strategy to control the site selectivity in radical-mediated C-H transformations. Employing non-site-selective hydrogen atom abstraction and donation catalysts synergistically led to a valuable site-selective reaction, allowing direct cyano group relocation to un-activated C-H sites.
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