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Microstructure and mechanical performance of low-cost biomedical-grade Titanium-316L alloy

Chowdhury Ahmed Shahed, Faiz Ahmad, Ebru Gunister, Khurram Altaf, Saad Ali, Abbas Raza, Khurshid Malik, Waseem Haider

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T(2023)

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Abstract
A 316L stainless steel (SS) alloy was developed with 1, 3, and 5 vol% titanium (Ti) reinforcement using the powder injection molding route, representing a low-cost option for biomedical implants. The investigation encompassed 1300 degrees C, 1350 degrees C, and 1380 degrees C sintering temperatures to ascertain the optimal physical and me-chanical properties. Both sintering temperature and Ti influenced sintered density, and Ti mitigated the dele-terious effects of residual carbon. At higher sintering temperatures, carbon and silicon tended to migrate and accumulate at the brink of Ti, leading to the formation of intermetallic compounds and increased brittleness. Dispersed Ti particles within the 316L matrix acted as nucleation sites and enhanced solid solubility with improved density. An astounding 96.11 % sintered density was achieved at 3 vol% Ti sample sintered at 1380 degrees C. During the tensile test, 5 vol% Ti at 1380 degrees C exhibited a low modulus of 58.9 GPa, which is highly desirable for orthopedic implant application. The XRD, SEM, tensile test, and nano-indentation results collectively provide evidence of beta-titanium formation during the sintering process. Conversely, the sample incorporating 3 vol% titanium, sintered at 1380 degrees C, demonstrated a balanced performance, showcasing 432.94 +/- 12.8 MPa ultimate tensile strength, 3.06 +/- 0.17 % elongation, 74.2 GPa modulus, and 322 MPa and 423 MPa 0.2 % offset flexural and compressive yield strengths, respectively. Notably, an improvised wear resistance test underscored its aptitude for sliding wear resistance, solidifying its potential as a promising candidate for biomedical implants.
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Key words
Biomedical implants,Beta titanium,Powder injection molding,Transgranular crack,Wear resistance,316L stainless steel
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