Cobalt Phosphide Nanoparticles Synthesized by Solvothermal Phosphidization of Metal-Organic Frameworks for Electrocatalytic Oxygen Evolution
INTERNATIONAL JOURNAL OF ENERGY RESEARCH(2023)
摘要
Active and stable electrocatalysts for oxygen evolution reaction (OER) are crucial in the widespread application of water electrolyzers. Cobalt phosphide nanoparticles (Co-P) with different degrees of crystallinity are synthesized via solvothermal phosphidization of Co metal-organic frameworks and P-4 using different solvents. The Co-P can be converted to active OER electrocatalysts in 1 M KOH, with the most active reaching 10 mA cm(-2) OER current densities at 270 mV overpotential. The OER intermediate adsorption energy is tuned by the electron interactions in the crystalline/amorphous heterostructured Co-P, which show the highest intrinsic OER activity. After the long-term OER in base, surface phosphides are converted to (oxy)hydroxides that are the active species towards OER.
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关键词
solvothermal phosphidization,nanoparticles,cobalt,metal-organic
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