Polyvalent chromium ions state in new Ca3(VO4)2:Cr single crystal

M.E. Doroshenko,L.I. Ivleva,I.S. Voronina,E.E. Dunaeva

Journal of Luminescence（2023）

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摘要

New high optical quality calcium orthovanadate Ca3(VO4)2 crystal doped by chromium ions was synthesized. Polyvalent character of doping chromium ions in as-grown crystal was revealed. Crystal annealing at 1000 °C seems to result in increase of chromium ions in four plus state. Spectroscopic properties of chromium ions in Ca3(VO4)2 crystal were investigated.

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关键词

Czochralski growth,Transition metals,Chromium ions,Laser spectroscopy,Luminescence

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