Ring size-reactivity relationship in radical ring-opening copolymerisation of thionolactones with vinyl pivalate
Polymer Chemistry(2022)
摘要
The radical ring-opening copolymerisation (rROcoP) of unsubstituted thionolactones of different ring sizes, namely γ-thionobutyrolactone (TBL), δ-thionovalerolactone (TVL), ε-thionocaprolactone (TCL) and ω-thionopentadecalactone (TPDL), with vinyl pivalate has been mechanistically investigated. The...
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关键词
copolymerisation,thionolactones,vinyl pivalate,size-reactivity,ring-opening
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